Pubblicazioni

Prof. GUIDO PAMPALONI

ELENCO DELLE PUBBLICAZIONI SCIENTIFICHE

1)         F. Calderazzo, D. Vitali, G. Pampaloni, I. Collamati, Reaction of Pentacarbonyliron(0) with Phthalodinitrile in Dimethylformamide and Isolation of Carbonyl Derivatives of Iron(II) Phthalocyanine Stabilized by Group 6 Donor Atoms, J. Chem. Soc., Chem. Commun., 221 (1979).

2)         F. Calderazzo, G. Pampaloni, D. Vitali, G. Pelizzi, I. Collamati, S. Frediani, A.M. Serra, Carbonyl Derivatives of Phthalocyaninatoiron((II), Expecially those Containing Group 6 Axial Donor Atoms. Crystal and Molecular Structure of (N,N-Dimethylformamido)Carbonyl-Pthalocyaninatoiron(II) and Mössbauer Spectra of Some of the Products, J. Organomet. Chem., 191, 217 (1980). (Fascicolo dedicato al Prof. H. Behrens in occasione del suo 65¡  compleanno).

3)         F. Calderazzo, G. Pampaloni, D. Vitali, I. Collamati, G. Fares, V. Dessy, Bis-Adducts of Phthalocyaninatoiron(II) with Group 6 Donor Atoms. Crystal and Molecular Structure of Bis(Dimethylsulphoxide) Phthalocyaninatoiron(II), DMSO Solvated, J. Chem. Soc., Dalton Trans., 1965 (1980).

4)         F. Calderazzo, G. Pampaloni, D. Vitali, Some new Results on the Hexacarbonyls of Vanadium, Gazz. Chim. Ital., 111, 455 (1981).

5)         F. Calderazzo, G. Pampaloni, D. Vitali, P.F. Zanazzi, The Reaction of Hexacarbonylvanadium with Aromatic Compounds. Part 4. Properties of [V(CO)4Arene]+ Cations and Crystal and Molecular Structure of [VDurene(CO)4] [V(CO)6] , J. Chem. Soc., Dalton Trans., 1993 (1982).

6)         F. Calderazzo, S. Frediani, B.R. James, G. Pampaloni, K.J. Reimer, J.R. Sams, A.M. Serra, D. Vitali, Synthesis and Mš ssbauer Spectra of Carbonyl Derivatives of Phthalocyaninatoiron(II), Inorg. Chem., 21, 2302 (1982).

7)         F. Calderazzo, G. Pampaloni, G. Pelizzi, The Hexacarbonylniobate(-I) Anion, J. Organomet. Chem., 233, C41 (1982).

8)         G.E. Herberich, G. Pampaloni, (h5-Divinylboran)metall Komplexe von Ruthenium und Rhodium, J. Organomet. Chem., 240,121 (1982).

9)         F. Calderazzo, G. Pampaloni, P.F. Zanazzi, Anomalous Behaviour of [Nb(CO)6] and  [Ta(CO) 6] towards Protons. Crystal and Molecular Structure of the Organometallic Acid [C4H8OH] [Nb2(CO)8Cl3] * C4H8O, J. Chem. Soc., Chem. Commun., 1304 (1982).

10)       F. Calderazzo, U. Englert, G. Pampaloni, G. Pelizzi, R. Zamboni, Studies on Early Transition Metal Carbonyl Derivatives. A Convenient Method for the Preparation of the [Nb(CO)6] Anion at Atmospheric Pressure and Room Temperature. Crystal and Molecular Structure of [M(CO)6] (M=Nb,Ta) as their Bis(Triphenylphospino)iminium(+1) Derivatives, Inorg. Chem., 22, 1865 (1983).

11)       F. Calderazzo, G. Pampaloni, A New Method for the Preparation of Some Carbonyl Metalate Anions, J. Organomet. Chem., 250, C33 (1983).

12)       F. Calderazzo, G. Pampaloni, Redox Reaction with Metal Carbonyls of Group V, J. Chem. Soc., Chem. Commun., 1249 (1984).

13)       F. Calderazzo, G. Pampaloni, Sodium Hexacarbonylniobate(-I), Inorg. Synth., 23, 34 (1984).

14)       F. Calderazzo, M. Castellani, G. Pampaloni, P.F. Zanazzi,  New Carbonyl Derivatives of Niobium(I) and Tantalum(I), J. Chem. Soc., Dalton Trans., 1989 (1985).

15)       F. Calderazzo, M. Lanfranchi, G. Pampaloni, G. Pelizzi, Proton- and Carbonyl-Mediated Electron Transfer Processes from the Hexacarbonyl-vanadate(-I) Anion, J. Organomet. Chem., 296, 1 (1985). (Fascicolo dedicato al Prof. L. Malatesta).

16)       F. Calderazzo, G. Pampaloni, Metal Carbonyl Complexes of Group Vb Metals, J. Organomet. Chem., 303, 111 (1986).

17)       F. Calderazzo, G. Pampaloni, P.F. Zanazzi, Redox Reactions with Metal Carbonyls of Group V, Chem. Ber., 119, 2796 (1986).

18)       P. Biagini, F. Calderazzo, G. Pampaloni, P.F. Zanazzi, Reactions of Group IVb (Group 4) Metal Derivatives with Bis-cyclopentadienylcobalt(II) and its Permethylated Analogue, Effect of Halide, Solvent and Metal, Gazz. Chim. Ital., 117, 27 (1987). (Fascicolo dedicato al Prof. E. Weiss in occasione del 60° compleanno).

19)       F. Calderazzo, G. Pampaloni, Reactions of Hexacarbonyl Derivatives of Group 5 Metals (V,Nb,Ta) with 9,10-Phenanthrenequinone, J. Organomet. Chem., 330, 47 (1987). (Fascicolo dedicato al Prof. L. Sacconi).

20)       P. Biagini, F. Calderazzo, G. Pampaloni, New Organometallic Derivatives of Titanium(II) containing p-Acids as Ligands, J. Chem. Soc. Chem. Commun., 1015 (1987).

21)       F. Calderazzo, G. Pampaloni, Sodium Hexacarbonylvanadate(-I), Organomet. Synth., R.B. King e J.J. Eisch, Eds., Elsevier Sequoia, S.A., Losanna, 4, 46 (1988).

22)       F. Calderazzo, G. Pampaloni, Hexacarbonylvanadium(0), Organomet. Synth., R.B. King e J.J. Eisch, Eds., Elsevier Sequoia, S.A., Losanna, 4, 49 (1988).

23)       P. Biagini, F. Calderazzo, G. Pampaloni, Bis(h5-Cyclopentadienyl)(dicarbonyl)titanium(II),  Organomet. Synth., R.B. King e J.J. Eisch, Eds., Elsevier Sequoia, S.A., Losanna, 4, 12 (1988).

24)       F. Calderazzo, G. Pampaloni, G. Pelizzi, F. Vitali, Synthesis of Hexacarbonyl Derivatives of Group 5 Metals and Electron Transfer Processes. Crystal and Molecular Structure of Tetracarbonyl(1,2-bis(diphenylphosphino)ethaneiodo tantalum, Organometallics, 7, 1083 (1988).

25)       F. Calderazzo, G. Pampaloni, G. Pelizzi, F. Vitali, Redox Reactions involving Hexacarbonylvanadium(0) and Compounds containing Element-Halide, Element-Hydrogen and Element-Carbon Bonds. Synthesis, Crystal and Molecular Structure of Ph3PbV(CO)6, Polyhedron, 7, 2039 (1988).

26)       P. Biagini, F. Calderazzo, G. Pampaloni, Synthesis and reactivity of Titanium(II) Arene Complexes, J. Organomet. Chem., 355, 99 (1988). (Fascicolo dedicato al Prof. E.O. Fischer in occasione del 70° compleanno).

27)       F. Calderazzo, U. Mazzi, G. Pampaloni, R. Poli, F. Tisato, P.F. Zanazzi, Reduction of Ammonium Pertechnetate and Ammonium Perrhenate by CO: Synthesis of M2(CO)10 (M = Tc, Re) and Crystal and Molecular Structure of the Trinuclear Cyanide-Bridged Derivative Re3(CN)3(CO)12, Gazz. Chim. Ital., 119, 241 (1989).

28)       F. Calderazzo, G. Pampaloni, U. Englert, J. Strähle, Stabilization of Niobium(0) and Tantalum(0) in Mixed Metal Clusters containing Silver Atoms, Angew. Chem., Int. Ed. Engl., 28, 471 (1989); Versione tedesca: Angew. Chem., 101, 469 (1989)

29)       F. Calderazzo, F. Marchetti, G. Pampaloni, W. Hiller, H. Antropiusová , K. Mach, Reactivity of Titanium(II) Arene Derivatives with substituted Alkynes. Cyclooligomerization Reactions and Crystal and Molecular Structure of Ti(h4-Ph4C4)[(m-Br)2(AlBr2)]2, Chem. Ber., 122, 2229 (1989).

30)       F. Calderazzo, G. Pampaloni, U. Englert, J. Stráhle, Electron-Transfer Processes with substituted Group 5 Metal Carbonyls. Synthesis, Crystal and Molecular Structure of Ag3M3(CO)12(Me2PCH2CH2PMe2)3 – M=Nb, Ta- the first structurally characterized derivative of Nb(0) and Ta(0), J. Organomet. Chem., 383, 45 (1990). (Fascicolo speciale pubblicato in occasione della scoperta del nickel carbonile)

31)       F. Calderazzo, P. Pallavicini, G. Pampaloni, Arene Derivatives of Zirconium and Hafnium(II), J. Chem. Soc., Dalton Trans.,1813 (1990).

32)       F. Calderazzo, G. Pampaloni, P. Pallavicini, P.F. Zanazzi, Heavier Halides of Early Transition Elements by Halide Exchange Reactions. Crystal and Molecular Structure of [Ph3C]2[Hf2Cl10] , J. Chem. Soc., Dalton Trans., 2743 (1990).

33)       F. Calderazzo, G. Pampaloni, Sodium Hexacarbonylniobate(-I), Inorg. Synth., 28, 192 (1990).

34)       F. Calderazzo, G. Pampaloni, L. Rocchi, J. Strähle, K. Wurst, The Reduction with Aluminum of the NbX5/AlX3 System in the Presence of Aromatic Hydrocarbons: an Entry to Niobium(II), Niobium(I) and Niobium(O) Organometallics, Angew. Chem., Int. Ed. Engl., 30, 102 (1991); Angew. Chem., 103, 109 (1991).

35)       F. Calderazzo, S. Ianelli, G. Pampaloni, G. Pelizzi, M. Sperrle, Synthesis of N,N-dialkylcarbamato Complexes of Group 4 Metals (Ti, Zr, Hf) by the Metal Chloride/R2NH/CO2 System: Crystal and Molecular Structure of Hf(O2CNPri2)4, J. Chem. Soc. Dalton Trans., 693 (1991). (Fascicolo speciale in occasione del 150° anniversario della fondazione della Royal Society of Chemistry).

36)       F. Calderazzo, G. Pampaloni, P. Pallavicini, J. Strähle, K. Wurst, Reactions of (h6-benzene)Zr(AlCl4)2 with Alkynes. Cyclooligomerization  Reactions and Crystal and Molecular Structure of the Seven-membered metallacycle [Zr-CPh-(CPh)4-CPh][(m-Cl)2(AlCl2)]2, Organometallics, 10, 896 (1991).

37)         F. Calderazzo, G. Pampaloni, L. Rocchi, J. Strähle, K. Wurst, Synthesis and Reactivity of h6-arene Derivatives of Niobium(II), Niobium(I) and Niobium(O), J. Organomet. Chem., 413, 91 (1991). (Fascicolo dedicato al Prof. P.L. Pauson).

38)       F. Calderazzo, G. Pampaloni, L. Rocchi, F. Marchetti, Crystal and Molecular Structure of [V(h6-1,3,5-Me3C6H3)2]AlCl4, the Primary Product of the Reduction of VCl3 by Al/AlCl3/1,3,5-Me3C6H3 and its further Reduction to V(h6-1,3,5-Me3C6H3)2., J. Organomet. Chem., 417, C16 (1991). (Fascicolo dedicato alla memoria del Prof. P. Pino).

39)       F. Calderazzo, G. Pampaloni, Organometallics of Group 4 and 5: oxidation states II or lower, J. Organomet. Chem., 423, 307 (1992).

40)       F. Calderazzo, G. Pampaloni, M. Sperrle, U. Englert, Electron- and Ligand-Transfer Reactions Involving N,N-Dialkylcarbamates. Synthesis and Molecular Structure of V2[h5-(C5H5)]2[O2CN(C2H5)2]4, Z. Naturforsch., 47b, 389 (1992).

41)       F. Calderazzo, F. Gingl, G. Pampaloni, L. Rocchi, J. Strähle, Synthesis and Reactivity of Mixed Arene-Halides of Niobium(I). Crystal and Molecular Structure of Nbmes2 and [Nbmes2(CO)][Nb2(m-I)3(CO)8], Chem. Ber., 125, 1005 (1992).

42)       F. Calderazzo, C. Felten, G. Pampaloni, D. Rehder, New Niobium Complexes with Alkynes. Crystal and Molecular Structure of NbI(CO)2(h2-MeCCMe)(PEt3)2, J. Chem. Soc., Dalton Trans., 2003 (1992).

43)       F. Calderazzo, U. Englert, G. Pampaloni, L. Rocchi, Nb[(h6-C6H5)2B(C6H5)2](h2-H3CC2CH3): the first example of a compound containing the bent, uninegative, 12-electron donor, tetraphenylborate ligand, Angew. Chem. Int. Ed. Engl., 31, 1235 (1992); versione tedesca: Angew. Chem., 104, 1230 (1992); .

44)       C. Felten, D. Rehder, G. Pampaloni, F. Calderazzo, Bis(alkyne) complexes of niobium(I) containing the alkyne as a 3-electron donating ligand, Inorg. Chim. Acta, 202, 121 (1992).

45)       F. Calderazzo, R. Invernizzi, F. Marchetti, F. Masi, A. Moalli, G. Pampaloni, L. Rocchi, h6-Arene Metal Complexes. Synthesis, reactivity and crystal and molecular structure [V(h6-1,3,5-Me3C6H3)2]AlCl4 and the one-pot synthesis of V(h6-1,3,5-Me3C6H3)2, Cr(h6-MeC6H5)2 and Mo(h6-MeC6H5)2, Gazz. Chim. Ital., 123, 53 (1993).

46)       F. Calderazzo, C. Maichle-Moessmer, G. Pampaloni, J. Strähle, Low temperature syntheses of vanadium(III) and molybdenum(IV) bromides by halide exchange and the crystal and molecular structure of mer-MoBr3(THF)3, J. Chem. Soc., Dalton Trans., 655 (1993).

47)       F. Calderazzo, G.E. De Benedetto, G. Pampaloni, C. Maichle-Moessmer, J. Strähle, K. Wurst, Bis(arene)vanadium(0) complexes as a source if vanadium(II) derivatives by both disproportionation of the [V(h6-arene)2]+ cations and oxidation of V(h6-arene)2, J. Organomet. Chem., 451, 73 (1993). (Fascicolo dedicato al Prof. G.P. Chiusoli in occasione del 70° compleanno).

48)       F. Calderazzo, G.E. De Benedetto, G. Pampaloni, L. Rocchi, U. Englert, Redox Reactions of Vanadium(0) and Niobium(0) bis-Mesitylene (mes) Derivatives with Metal Carbonyl Halides of Group 7. The Crystal and Molecular Structure of mes(CO)2Nb(m-I)2Re(CO)3, a Metal-Metal Bonded Heterobimetallic Complex, J. Organomet. Chem., 462, C10 (1993). (Fascicolo dedicato al Prof. M.F. Lappert in occasione del 65° compleanno).

49)       F. Calderazzo, U. Englert, A. Guarini, F. Marchetti, G. Pampaloni A. Segre, Zr3Cp2(O2CNPri2)6(m3-O)(m2-CCO), the first crystallographically established ketenylidene complex obtained by a metal-assisted deoxygenation of coordinated carbon monoxide. A new possible model for chemisorbed CO on reducing metal-based matrices, Angew. Chem. Int. Ed. Engl., 33, 1188 (1994); Angew. Chem., 106, 1254 (1994).

50)       F. Calderazzo, G. Pampaloni, L. Rocchi, U. Englert, Synthesis, Reactivity and Crystal and Molecular Structures of Nb(L)(h6-C6H5-nXn)2B(C6H5-nXn)2, a Class of Mononuclear Metal Compounds Containing the 12-Electron Donor Tetraarylborato Ligand, Organometallics, 13, 2592 (1994).

51)       G. Pampaloni, U. Kölle, Chemical and Electrochemical Studies on Metal Carbonyl / Cobaltocene Systems, J. Organomet. Chem., 481, 1 (1994)

52)       F. Calderazzo, G. Pampaloni, A. Vallieri, Synthesis, Spectroscopic Studies and Reactivity of h6-Arene Derivatives of Titanium(IV), Inorg. Chim. Acta, 229, 179 (1995). (Fascicolo dedicato al Prof. F.A. Cotton in occasione del 65°  compleanno).

53)       G. Pampaloni, U. Englert, Tetrahydrofuran and 1,2-Dimethoxyethane Derivatives of Vanadium(III) and Vanadium(II), Inorg. Chim. Acta, 231, 167 (1995).

54)       F. Calderazzo, G. Pampaloni, Aromatic Hydrocarbons, Carbocyclic Ligands Spanning Several Oxidation States in both Main Group and Transition Elements. Recent Advances with Early Transition d Elements, J. Organomet. Chem., 500, 47 (1995). (review su invito).

55)       D. Belli Dell’Amico, F. Calderazzo, F. Marchetti, G. Pampaloni, Stoichiometric and Exaustive Hydrolysis of N,N-dialkylcarbamates, Aqueous Organometallic Chemistry and Catalysis, I.T. Horváth e F. Joó , Ed., Kluwer Academic Publisher, 1995, p.199.

56)       F. Calderazzo, G. Pampaloni, Organometallics of Early Transition Elements, Syntheses and Methodologies in Inorganic Chemistry, S. Daolio, E. Tondello, P.A. Vigato, Eds., 5, 37-52 (1995).

57)       P. B. Arimondo, F. Calderazzo, U. Englert, C. Maichle-Mössmer, G. Pampaloni, J. Strähle, Preparation and Characterization of N,N-Dialkylcarbamato Derivatives of Niobium and Tantalum, J. Chem. Soc., Dalton Trans., 311 (1996).

58)       F. Calderazzo, U. Englert, A. Guarini, F. Marchetti, G. Pampaloni, A. Segre, G. Tripepi, Zirconium(II)- and Hafnium(II)-Assisted Reductive Coupling of Coordinated Carbonyl Groups Leading to Ketenylidene Complexes of Zirconium(IV) and Hafnium(IV), Chem. Eur. J., 2, 412 (1996).

59)       F. Calderazzo, G. De Benedetto, U. Englert, I. Ferri, G. Pampaloni, T. Wagner, New Preparative Methods for the Halides of Titanium(II) and Vanadium(II): Reduction of Titanium(IV) Halides with Sodium and Oxidation of Bis(mesitylene)vanadium(0)., Z. Naturfosch., 51b, 506 (1996).

60)       F. Calderazzo, I. Ferri, G. Pampaloni, S. Troyanov, Synthesis of h6-Arene Derivatives of Zirconium(IV) and Hafnium (IV), J. Organomet. Chem. 518, 189 (1996). (Fascicolo dedicato al Prof. E. Weiss in occasione del 70¡  compleanno).

61)       F. Calderazzo, I. Ferri, G. Pampaloni, U. Englert e M.L.H. Green, Synthesis of [Ti(h6-1,3,5-C6H3iPr3)2][BAr4], [Ar = C6H5, p-C6H4F, 3,5-C6H3(CF3)2], the First Titanium (I) Derivatives, Organometallics, 16, 3100 (1997).

62)       F. Calderazzo, U. Englert, G. Pampaloni, U. Kölle e G. Tripepi, Redox Reactions of Low-Valent Group 4 Organometallics with 9,10-Phenanthrenequinone (PQ). Crystal and Molecular Structure of a Ten-Membered Tetraoxametallacycle of Bis(cyclopentadienyl) zirconium(IV), J. Organomet. Chem., 543, 201 (1997).

63)       U. Englert, F. Calderazzo, G. Pampaloni, Topotactic reversible phase transition between room-temperature and a new low-temperature modification in the MCl3(THF)3 system, Struct. Chem., 8, 237 (1997).

64)       F. Calderazzo, G. E. De Benedetto, S. Detti, G. Pampaloni, Synthesis of Protonated Carboxylato- and Trifluoro-methanesulfonato Derivatives of Vanadium(II) by Redox Reactions on Bis(1,3,5-trimethylbenzene)vanadium(0), J. Chem. Soc., Dalton Trans., 3319 (1997) (Fascicolo dedicato alla memoria del Prof. Sir Geoffry Wilkinson).

65)       F. Calderazzo, G. Pampaloni, G. Tripepi, The titanocene dicarbonyl dication [TiCp2(CO)2]2+, Organometallics, 16, 4943 (1997).

66)       F. Calderazzo, U. Englert, C. Maichle-Mössmer, F. Marchetti, G. Pampaloni, D. Petroni, C. Pinzino, J. Strähle, G. Tripepi, Eight Coordinate Chelate Complexes of Zirconium(IV) and Niobium(IV): X-Ray Diffractometric and EPR Investigations, Inorg. Chim. Acta, 270/1-2, 177 (1998) (fascicolo dedicato al Prof. J. Halpern).

67)       F. Calderazzo, U. Englert, G. Pampaloni, G. Tripepi, The Tetracyclopentadienyls of Titanium, Zirconium and Hafnium: New Synthetic Procedures and Reactivity, J. Organomet. Chem., 555, 49 (1998)

68)       L. Abis, F. Calderazzo, C. Maichle-Mössmer, G. Pampaloni, J. Strähle, e G. Tripepi, Cyclopentadienyl-N,N-diethylcarbamato Derivatives of Zirconium(IV) and Hafnium(IV), MCp(O2CNEt2)3: Synthetic Procedures and Use as Precursors for the Chemical Implantation of Organometallic Fragments on a Silica Surface, J. Chem. Soc., Dalton Trans., 841 (1998).

69)       P. Bernieri, F. Calderazzo, U. Englert, G. Pampaloni, Niobium(I) and Tantalum(I) Tetracarbonyl Derivatives Containing Nitrogen Ligands, J. Organomet. Chem., 562, 61 (1998) (fascicolo dedicato al Prof. B. King).

70)       P. B. Arimondo, F. Calderazzo, R. Hiemeyer, C. Maichle-Mössmer, F. Marchetti, G. Pampaloni, J. Strähle, Synthesis and Crystal Structure of a Self-Assembled, Octanuclear Oxo-Tantalum(V) Derivative containing the First Example of a Transition Metal M8(m-O)12 Cage, Inorg. Chem., 21, 5507 (1998).

71)       D. Belli Dell’ Amico, F. Calderazzo, F. Marchetti, G. Pampaloni, A New Supporting Ligand for m-Oxo Metal Derivatives: N,N-dialkylcarbamato, O2CNR2, “Metal Clusters in Chemistry”, Vol. 1, 209-220, P.Braunstein, L. Oro, P. Raithby, Eds., Wiley-VCH Verlag GmbH: Weinheim, Germany, 1999.

72) F. Calderazzo, I. Ferri, G. Pampaloni, U. Englert, Oxidation Products of Vanadocene and of its Permethylated Analogue including the Isolation and the Reactivity of the Unsolvated [VCp2]+ Cation, Organometallics, 18, 2452 (1999).

73)       F. Calderazzo, U. Englert, G. Pampaloni, E. Vanni, Tetra-, Penta-, and Hexacoordination in Iron(II) Adducts of Aliphatic Bidentate Amines. Crystal and Molecular Structure of the Mononuclear Complexes Fe(dienMe)Cl2 and Fe(tmeda)I2, Comptes Rendus Acad. Sci., t. 2, Série II c, 311 (1999) (Fascicolo speciale dedicato al Prof. R. Poilblanc).

74)       F. Calderazzo, M. D’Attoma, F. Marchetti, G. Pampaloni, S. I. Troyanov, Labile Adducts of TiCl4 with Thionyl Chloride Structurally Characterized at Low Temperature: a Comparison with the Zirconium and Hafnium Analogues, [MCl4(SOCl2)]2, J. Chem. Soc., Dalton Trans., 2275 (1999)

75)      F. Calderazzo, F. Marchetti, G. Pampaloni, V. Passarelli, Coordination Properties of 1,10–Phenanthroline–5,6–Dione Towards Group 4 and Group 5 Metals in Low- and High Oxidation States, J. Chem. Soc., Dalton Trans., 4389 (1999)

76)       G. Pampaloni, G. Tripepi, Carbon Monoxide and Tertiary Phosphines as Ligands in Cyclopentadienyl Derivatives of Group 4 Elements in High Oxidation State, J. Organomet. Chem., 593-594, 19 (2000) (Fascicolo speciale dedicato al Prof. F. Calderazzo).

77)       D. Belli Dell’Amico, R. Alessio, F. Calderazzo, F. Della Pina, U. Englert, G. Pampaloni, V. Passarelli, Synproportionation Reactions between Copper(II) Trihaloacetates Cu(CX3COO)2 , X = F, Cl, Br, and Copper in the Presence of Carbon Monoxide, J. Chem. Soc., Dalton Trans., 2067 (2000)

78)       F. Calderazzo, M. D’Attoma, G. Pampaloni, S.I. Troyanov, Reactivity of SeOCl2 with titanium and zirconium tetrachlorides. The unexpected formation of a m-oxo-bridged titanium(IV) derivative, J. Chem. Soc., Dalton Trans., 2497 (2000).

79)       A. Altomare, R. Candian, M. Michelotti, G. Pampaloni, F. Ciardelli, Bis(h5-cyclopentadienyl) bistriphenylsilanolatozirconium(IV): a new precursor for ethylene polymerization catalysis, e-Polymers, num. 008, p. 1, 2001

80)       F. Calderazzo, F. Marchetti, M. Moreno, G. Pampaloni, F. Tumminia, Fluorenyl derivatives of early transition elements: a synthetic and structural study, J. Organomet. Chem., 631, 110 (2001).

81)       F. Calderazzo, M. D’Attoma, G. Pampaloni, S.I.Troyanov, Reactions of chalcogen oxide chlorides EOCl2 (E = S, Se) with Group 5 metal chlorides, Z. Anorg. Allg. Chem., 627, 180, (2001).

82)       F. Calderazzo, U. Englert, G. Pampaloni, V. Passarelli, Synthesis and characterization of mono- and bi-metallic derivatives of Groups 4 and 5 with 2,5-dimethoxy-1,4-benzoquinone, J. Chem. Soc., Dalton Trans. , 2891 (2001).

83)       F. Calderazzo, C. Giardi, U. Englert, G. Pampaloni, Synthesis, characterization and reactivity of tetracyclopentadienylniobium(IV), a precursor to organometallic derivatives of niobium(IV), J. Organomet. Chem. , 630, 275 (2001).

84)       F. Calderazzo, U. Englert, G. Pampaloni, V. Passarelli, V, G. Serni, R.M. Wang, Synthesis, characterization, and reactivity of manganese(II) and iron(II) trifluoroacetates. Crystal and molecular structure of two linkage isomers of polynuclear [Mn(CF3COO)2(THF)2]n, Can. J. Chem., 79, 495 (2001).

85)       F. Calderazzo, G. Pampaloni, V. Passarelli, 1,10-phenanthroline-5,6-dione as a Building Block for the Synthesis of Homo- and Heterometallic Complexes, Inorg. Chim. Acta, 330, 136 (2002).

86)       D. Belli Dell’Amico, F. Calderazzo, L. Labella, F. Marchetti, G. Pampaloni, N,N-dialkylcarbamato metal complexes, molecular inorganic precursors to functionalized inorganic matrices, Inorg. Chem. Commun., 5, 733 (2002).

87)       F. Calderazzo, S. Falaschi, F. Marchetti, G. Pampaloni, Carbonyl Derivatives of Iron(0) from the Reaction of FeR2(bipy)2 (R = Me, Et) with Carbon Monoxide, J. Organomet. Chem. 662, 137 (2002).

88)       F. Calderazzo, U. Englert, C. Hu, F. Marchetti, G. Pampaloni, V. Passarelli, A. Romano, R. Santi, Synthesis and Structural Characterization of Iron(II) Derivatives of Heterocyclic Tridentate Amines, Inorg. Chim. Acta,  344, 197-206 (2003), Paper dedecated to Professor Mauro Graziani.

89)       F. Calderazzo, N. Donati, U. Englert, F. Marchetti, G. Pampaloni, V. Passarelli, Synthesis, Reactivity and Structures of Mono- and Dihaloacetato Derivatives of Copper(I) and Copper(II), Inorg. Chim. Acta, 346, 100-110 (2003).

90)       D. Belli Dell’Amico, F. Calderazzo, L. Labella, F. Marchetti, G. Pampaloni, Converting Carbon Dioxide into Carbamato Derivatives, Chem. Rev., 103, 3857 (2003).

91)       F. Calderazzo, M. Guelfi, G. Pampaloni, Olefin and CO Competition equilibria for Bis(cyclopentadienyl)vanadium(II), Organometallics, 23, 1519 (2004).

92)       F. Calderazzo, C. Forte, F. Marchetti, G. Pampaloni, L. Pieretti, Reaction of Phenanthrene-9,10-dione with Phenanthrene-9,10-diol: Synthesis and Characterization of the First ortho-Quinydrone Derivative, Helv. Chim. Acta, 87, 781 (2004).

93)       S. Antonini, F. Calderazzo, U. Englert, E. Grigiotti, G. Pampaloni, P. Zanello, Synthesis, Electrochemistry, and Crystal and Molecular Structures of Some Molybdenum(0) Arene Derivatives with fluorinated and Phenyl-Substituted Arene Ligands, J. Organomet. Chem., 689, 2158 (2004).

94)       P. Biagini, F. Calderazzo, F. Marchetti, G. Pampaloni, S. Ramello, M. Salvalaggio, Roberto Santi and S. Spera, Mono- and Dinuclear Complexes of Sulfones with the Tetrachlorides of Group 4, Dalton Trans., 2364 (2004).

95)       F Calderazzo, U. Englert, G. Pampaloni, R. Santi, A. Sommazzi, M. Zinna, Bis(arylimino)pyridine Derivatives of Group 4 Metals: Preparation, Characterization and Activity in Ethylene Polymerization, Dalton Tans., 914 (2005)

96)       G. Pampaloni, R. Peloso, C. Graiff, A. Tiripicchio, Olefin Trifluoroacetato Derivatives of Copper(I) and Their Olefin/CO Exchange Reaction, Organometallics, 24, 819 (2005).

97)       G. Pampaloni, R. Peloso, C. Graiff, A. Tiripicchio, Synthesis, Characterization and Olefin/CO Exchange Reactions of Copper(I) Derivatives Containing Bidentate Oxygen Ligands, Organometallics, 24, 4475 (2005).

98)       F. Calderazzo, U. Englert, G. Pampaloni, M. Volpe, Redox Reactions with Bis(h6-Arene) Derivatives of Early Transition Metals, J. Organomet. Chem, 690, 3321 (2005)

99)     F. Calderazzo, F. Masi, G. Pampaloni, V. Passarelli, R. Santi, A. Sommazzi, S. Spera, F. Tumminia, Perfluorofluorenyl Anions and their Use as Co-Catalysts in the Zirconocene-Promoted Polymerization of Olefins, , J. Organomet. Chem, 690, 4886 (2005).

100)    L. Calucci, U. Englert, G. Pampaloni, C. Pinzino, M. Volpe, Reactivity of Bis(h6-Arene) Derivatives of Titanium, Vanadium and Niobium with Fulvenes bearing Electron-Withdrawing Substituents, , J. Organomet. Chem, 690, 4844 (2005).

101)     F. Benetollo, E. Grigiotti, F. Laschi, G. Pampaloni, M. Volpe, P. Zanello, Electrochemical and EPR investigation on Bis-Toluene Cr(I) complex [Cr(h6-CH3C6H5)2][dbcp−NO2], ([dbcp−NO2]ƒ{ = 1,2-dibenzoyl-4-nitrocyclopentadienyl Anion: the First Example of a Complex [Cr(h6-CH3C6H5)2]+ Cation Containing a cis-Eclipsed Arrangement of Toluene Rings, J. Sol. State Electrochem., 9, 732 (2005).

102)     L. Calucci,  U. Englert, E. Grigiotti, F. Laschi, G. Pampaloni, C. Pinzino, M. Volpe, P. Zanello, Synthesis and characterization of Chromium(I) Bis(h6-toluene) Derivatives Containing Sterically Demanding Anions, J. Organomet. Chem, 691, 829 (2006).

103)     G. Pampaloni, R. Peloso, C. Graiff, A. Tiripicchio, Synthesis, Characterization and Olefin/CO Exchange Reactions of Pyrazolylborato Complexes of Copper(I), Dalton Trans., 3576 (2006)

104)     F. Marchetti, G. Pampaloni, C. Pinzino, Some New Results on the Fischer-Hafner Synthesis of Vanadium Arenes, J. Organomet. Chem., 691, 3458 (2006).

105)    L. Calucci F. G. N. Cloke, U. Englert, P. B. Hitchcock, G. Pampaloni, C. Pinzino, F. Puccini, M. Volpe, Synthesis of Chromium(0) and Molybdenum(0) Bis (h6-arene) Derivatives and Their Monoelectronic Oxidation to [M(h6-arene)2]+ Cations, Dalton Trans., 4228, 2006.

106)   L. Calucci, G. Pampaloni, C. Pinzino, A. Prescimone, Transition Metal Derivatives of 1,10-Phenanthroline-5,6-dione: Controlled Growth of Coordination Polynuclear Derivatives, Inorg. Chim. Acta, 359, 3911 (2006).

107)    A. Boni, G. Pampaloni, R. Peloso, D. Belletti, C. Graiff and A. Tiripicchio, Synthesis of Copper(I) bis(3,5-dimethylpyrazolyl)methane olefin complexed and their reactivity towards carbon monoxide, J. Organomet. Chem., 691, 5602 (2006).

108)    F. Marchetti, F. Marchetti, B. Melai, G. Pampaloni , S. Zacchini, Synthesis and Reactivity of Haloacetato Derivatives of Iron(II) Including the Crystal and the Molecular Structure of [Fe(CF3COOH)2(m-CF3COO)2]n, Inorg. Chem., 46, 3378 (2007).

109)    U. Englert, G. Pampaloni, F. Puccini, M. Volpe, One-Electron Redox Reactions Involving Chromium(0) and Molybdenum(0) Bis-1,3,5-Trimethylbenzene Derivatives, J. Organomet. Chem., 692, 3144 (2007).

110)    A. Albinati, F. Calderazzo, F. Marchetti, S. A. Mason, B. Melai, G. Pampaloni, S. Rizzato, A trinuclear trifluoroacetato anion of iron(II) containing a central O(–I) ligand,  Inorg. Chem. Commun., 10, 902 (2007).

111)    G. Pampaloni, R. Peloso, D. Belletti, C. Graiff, A. Tiripicchio, Trifluoromethyl-substituted Bis(Pyrazolyl)Methanes as Ligands for Copper and Silver: Synthesis and Spectroscopic and Structural Characterization, Organometallics, 26, 4278 (2007).

112)    F. Marchetti, G. Pampaloni, S. Zacchini, Reactivity of Niobium(V) and Tantalum(V) Halides with Carbonyl Compounds: Synthesis of Simple Coordination Adducts, C–H bond Activation, C=O Protonation, and Halide Transfer, Dalton Trans., 4343 (2007).

113)    F. Marchetti, G. Pampaloni, S. Zacchini, The Reactivity of Niobium and Tantalum Pentahalides with Cyclic Ethers and the Isolation and the Characterization of Intermediates in the Polymerization of Tetrahydrofuran, Inorg. Chem., 47, 365 (2008).

1143)  F. Marchetti, G. Pampaloni, S. Zacchini, Complexes of Niobium(V) and Tantalum(V) Halides with Ligands containing N–C=O and P=O Functionalities: a Synthetic and Structural Study, Eur. J. Inorg. Chem., 453 (2008).

115)    F. Marchetti, G. Pampaloni, T. Repo, On the Polymerization of Tetrahydrofuran Initiated by Niobium(V) and Tantalum(V) Halides, Eur. J. Inorg. Chem., 2107 (2008).

116)    E. K. Brechin L. Calucci, U. Englert, L. Margheriti, G. Pampaloni, C. Pinzino, A. Prescimone, 1,10-Phenanthroline-5,6-dione Complexes of Middle Transition Elements: Mono- and Dinuclear Derivatives, Inorg. Chim. Acta, 361, 2375 (2008).

117)    F. Marchetti, G. Pampaloni, S. Zacchini, The Chemistry of Niobium and Tantalum Halides, MX5, with Haloacetic Acids and their Related Anhydrides. Anhydride C–H Bond Activation Promoted by MF5, Polyhedron, 27, 1969 (2008).

118)    D. Belli Dell’Amico, F. Calderazzo, G. Pampaloni, Heavier halides of transition metals by halide exchange, Inorg. Chim. Acta, 361, 2997 (2008).

119)    F. Marchetti, G. Pampaloni, S. Zacchini, From 1,2-Dialkoxyalkanes to 1,4-Dioxanes. A Transformation Mediated by NbCl5 via Multiple C–O Bond Cleavage at Room Temperature, Chem. Commun, 3651 (2008).

120)    F. Marchetti, G. Pampaloni and S. Zacchini, Unusual Room Temperature Activation of 1,2-Dialkoxyalkanes by Niobium and Tantalum Pentachlorides: Multiple Cleavage of C–O bonds and Formation of Oxychloride Complexes, Dalton Trans., 7026 (2008).

121)    G. Pampaloni, Inorganic Synthesis in Inorganic and Bio-Inorganic Chemistry, V. Bertini Ed., in Encyclopedia of Life Support Systems (EOLSS), Developed under the auspices of the UNESCO, EOLSS Publishers, Oxford, UK, 2008. [http:www.eolss.net].

122)    F. Marchetti, F. Marchetti, F. Masi, G. Pampaloni, V. Passarelli, A. Sommazzi, S. Spera, Synthesis, variable temperature NMR investigations and solid state characterization of novel octafluorofluorene compounds, J. Fluorine Chem., 130, 341 (2009).

123)    F. Marchetti, G. Pampaloni, S. Zacchini, Epoxide Ring Opening and Insertion into the M–X Bond of Niobium and Tantalum Pentahalides: Synthesis of Dihalide-tris(2-haloalcoholato) Complexes, Polyhedron, 28, 1235 (2009).

124)    G. Pampaloni, P. Zanello, Redox Chemistry and Electrochemistry of Metal Enolates in The Chemistry of Metal Enolates, J. Zabicky, Ed., J. Wiley, Chichester, England, 2009, pp. 461-550.

125)    F. Calderazzo, F. Masi, G. Pampaloni, Homonuclear and heteronuclear transition metal complexed by syn-proportionation reactions, Inorg. Chim. Acta, 362, 4291 (2009).

126)    F. Marchetti, G. Pampaloni, S. Zacchini, Fragmentations of Oxygen-containing Molecules via C–O Bonds Cleavage Promoted by Coordination to Niobium and Tantalum Pentahalides, Dalton Trans., 6759 (2009).

127)    F. Marchetti, G. Pampaloni, S. Zacchini, The Reactivity of 1,1-Dialkoxyalkanes with Niobium and Tantalum Pentahalides. Formation of Coordination Compounds, C–H and C–C Bonds Activation and the X-Ray Structure of the Stable Carboxonium Species [Me2C=CHC(=OMe)Me][NbCl5(OMe)], Dalton Trans., 8096-8106 (2009).

128)    A. M. Raspolli Galletti, G. Pampaloni, A. D’Alessio, Y. Patil, F. Renili, S. Giaiacopi, Novel highly active niobium catalysts for ring opening metathesis polymerization of norbornene, Macromol. Rapid Commun., 30, 1762-1768 (2009).

129)    L. Calucci, C. Forte, G. Pampaloni, C. Pinzino, F. Renili, Chemical Implantation of Group 4 Cations on Silica via Cyclopentadienyl- and N,N-Dialkylcarbamato Derivatives, Inorg. Chim. Acta, 363, 33 (2010).

130)    F. Marchetti, G. Pampaloni, S. Zacchini, 19F NMR Spectroscopy as Useful Tool for Determining the Structure in Solution of Coordination Compounds of MF5 (M = Nb, Ta), J. Fluorine Chem., 131, 21 (2010).

131)    G. Pampaloni, Coord. Chem. Rev., 254, 387 (2010).

132)    G. Pampaloni, Aromatic Hydrocarbons as Ligands. Recent Advances in the Synthesis, the Reactivity and the Applications of bis(h6-Arene) Complexes, Coord. Chem. Rev., 254, 402 (2010).

133)    A. M. Raspolli Galletti, G. Pampaloni, Niobium Complexes as Catalytic Precursors for the Polymerization of Olefins, Coord. Chem. Rev., 254, 525 (2010).

134)    R. Bini, C. Chiappe, F. Marchetti, S. Zacchini, G. Pampaloni, The Structures and the Unusual Rearrangements of Coordination Adducts of MX5 (M = Nb, Ta; X = F, Cl) with Simple Diethers. A Crystallographic, Spectroscopic and Computational Study, Inorg. Chem., 49, 339 (2010).

135)    F. Marchetti, G. Pampaloni, S. Zacchini, Preparation and Reactivity of Mono- and Dinuclear Derivatives of Niobium and Tantalum Pentahalides with Alkyl-Aryl-Ethers, Eur. J. Inorg. Chem., 767-774 (2010).

136)    S. Dolci, F. Marchetti, G. Pampaloni, S. Zacchini A Systematic Study on the Activation of Simple Polyethers by MoCl5 and WCl6, Dalton Trans., 39, 5367-5376 (2010).

137)    F. Marchetti, C. Pinzino, S. Zacchini, G. Pampaloni, Long-Lived Radical Cations of Monocyclic Arenes at Room-Temperature Obtained by NbF5 Acting as Oxidising Agent and Counterion Precursor, Angew. Chem. Int. Ed., 49, 5268-5272 (2010)

138)    P. Biagini, L. Bonoldi, F. Marchetti, G. Pampaloni, Halo-complexes of Titanium(III): the Thermochromic Behaviour of [NBu4][TiCl4(THF)2], Inorg. Chim. Acta, 363, 3637-3639 (2010).

139)    F. Marchetti, G. Pampaloni, Characterization and Thermal Activation of Adducts of Group 4 Tetrahalides with 1,2-Dialkoxyalkanes, Inorg. Chim. Acta, 363, 3670-3673 (2010).

140)    A. Boni, F. Marchetti, G. Pampaloni, S. Zacchini, Cationic Diiron and Diruthenium m-Allenyl Complexes: Synthesis, X-Ray Structures and Cyclization Reactions with Ethyldiazoacetate/Amine Affording Unprecedented Butenolide- and Furaniminium-Substituted Bridging Carbene Ligands, Dalton Trans., 39 108666-10875 (2010).

141)    C. Forte, G. Pampaloni, C. Pinzino, F. Renili, N,N-Dialkylcarbamato Derivatives of Niobium and Tantalum as Precursors to Metal-Functionalized Silica Surfaces, Inorg. Chim. Acta, 365, 251-255 (2011).

142)    F. Marchetti, G. Pampaloni, C. Pinzino, Room-temperature long-lived [Nb2F11] salts of radical cations of simple arenes: EPR, UV–Vis and DFT results, J. Organomet. Chem., 696, 1294-1300 (2011).

143)    F. Marchetti, G. Pampaloni, Y. Patil, A. M. Raspolli Galletti, S. Zacchini, Easily Available Niobium(V) Mixed Chloro-Alkoxide Complexes as Catalytic Precursors for Ethylene Polymerization, J. Polym. Sci., Part A: Polymer Chem., 49, 1664-1670 (2011).

144)    F. Marchetti, G. Pampaloni, Y. Patil, A. M. Raspolli Galletti, F. Renili, S. Zacchini, Ethylene Polymerization by Niobium(V) N,N-dialkylcarbamates Activated with Aluminum Co-catalysts, Organometallics, 30, 1682-1688 (2011).

145)    R. Bini, F. Marchetti, G. Pampaloni, S. Zacchini, Further Insights into the Chemistry of Niobium and Tantalum Pentahalides with 1,2-Dialkoxyalkanes: Synthesis of Bromo- and Iodoalkoxides, Spectroscopic and Computational Studies, Polyhedron., 30, 1412-1419 (2011).

146)    S. Dolci, F. Marchetti, G. Pampaloni, S. Zacchini, C-N Bond Forming Self-Condensation of Amide Promoted by MoCl5 at Room Temperature, Inorg. Chem., 50, 3846-3848 (2011).

147)    C. Forte, M. Hayatifar, G. Pampaloni, A. M. Raspolli Galletti, F. Renili, S. Zacchini, Ethylene Polymerization Using Novel Titanium Catalytic Precursors Bearing N,N-dialkylcarbamato Ligands, J. Polym. Sci., Part A: Polymer Chem., 49, 3338-3345 (2011).

148)    A. Boni, T. Funaioli, F. Marchetti, G. Pampaloni, C. Pinzino, S. Zacchini, Reversible Reductive Dimerization of Diiron m-Vinyl Complex via C-C Coupling: Characterization and Reactivity of the Intermediate Radical Species, Organometallics, 30, 4115-4122 (2011).

149)    F. Marchetti, G. Pampaloni, The Reactivity of NbX5 (X = F, Cl) with Lactons and Lactams, and the Synthesis of the First Nucleobase-Containing Niobium Complex, Inorg. Chim. Acta, 376, 123-128 (2011).

150)    A. Boni, T. Funaioli, F. Marchetti, G. Pampaloni, C. Pinzino, S. Zacchini, Electrochemical, EPR and computational results on [Fe2Cp2(CO)2]-based complexes with a bridging hydrocarbyl ligand, J. Organomet. Chem., 696, 3551-3556 (2011).

151)    F. Marchetti, G. Pampaloni, Y. Patil, A. M. Raspolli Galletti, M. Hayatifar, Easily-Available Oxygen-Containing Derivatives of Niobium Pentachloride as Catalytic Precursors for Ethylene Polymerization, Polym. Intern., 60, 1722-1727 (2011).

152)    M. Hayatifar, F. Marchetti, G. Pampaloni, Y. Patil, A. M. Raspolli Galletti, Room-temperature polymerization of b-pinene by niobium and tantalum halides, Catal. Today, 192, 177-182 (2012).

153)    F. Marchetti, G. Pampaloni, Interaction of Niobium and Tantalum Pentahalides with O-donors: Coordination Chemistry and Activation Reactions, Chem. Commun., 48, 635-653 (2012).

154)    F. Marchetti, G. Pampaloni, L. Biancalana, Activation Reactions of 1,1-Dialkoxoalkanes and Unsaturated O-Donors by Titanium Tetrafluoride, Inorg. Chim. Acta, 385 135-139 (2012).

155)    M. Bortoluzzi, N. Guazzelli, F. Marchetti, G. Pampaloni, S. Zacchini, Convenient synthesis of fluoride-alkoxides of Nb(V) and Ta(V): a spectroscopic, crystallographic and computational study, Dalton Trans., 41 12898-12906 (2012).

156)    S. Dolci, V. Ierardi, M. Remskar, Z. Jagličic, F. Pineider, A. Boni, G. Pampaloni C. A. Veracini, V. Domenici, Chemical–physical properties, morphology, and magnetic investigations on new cystine functionalized ultra-small super-paramagnetic iron-oxide nanoparticles, J. Mat. Sci., 48 1283-1291 (2013).

157)    F. Marchetti, G. Pampaloni, S. Zacchini, The Interaction of MoCl5 with Carbonyl Compounds, Dalton Trans., 42, 2477-2487 (2013).

158)    Fabio Marchetti, Guido Pampaloni, Calogero Pinzino, Filippo Renili, Timo Repo, Sirpa Vuorinen, Ring Opening Polymerization of rac-Lactide by Group 4 Tetracarbamato Complexes: Activation, Propagation and Role of The Metal, Dalton Trans., 42, 2792-2802 (2013).

159)    S. Dolci, F. Marchetti, G. Pampaloni, S. Zacchini, The Reactivity of Molybdenum Pentachloride with Ester Molecules: Ester Activation, Metal Reduction and Synthesis of 1D Coordination Polymers, Eur. J. Inorg. Chem., 1371-1380 (2013).

160)    S. Dolci, F. Marchetti, G. Pampaloni, S. Zacchini, Coordination Chemistry of WCl6: a Crystallographic and Spectroscopic Study on the Reactions with Carbonyl Compounds, Dalton Trans., 42, 5635-5648 (2013)

161)    M. Hayatifar, F. Marchetti, G. Pampaloni, Y. Patil, A. M. Raspolli Galletti, Fluoride adducts of Niobium(V): Activation Reactions and Alkene Polymerizations, Inorg. Chim. Acta, 399, 214-218 (2013).

162)    G. Agonigi, M. Bortoluzzi, T. Funaioli, F. Marchetti, G. Pampaloni, S. Zacchini, Synthesis of Diiron m-Allenyl Complexes by Electrophilic Addition to Propen-2-yl-Dimetallacyclopentenone Species: a Joint Experimental and DFT Study, J. Organomet. Chem., 731, 61-66 (2013).

163)    M. Hayatifar, F. Marchetti, G. Pampaloni, S. Zacchini, Synthesis, X-Ray Characterization and Reactivity of a-Aminoacidato Ethoxide Complexes of Niobium(V) and Tantalum(V), Inorg. Chem., 52, 4017-4025 (2013)

164)    M. Bortoluzzi, F. Ghini, M. Hayatifar, F. Marchetti, G. Pampaloni, S. Zacchini, Oxo- and Sulfido N,N-Diethylcarbamates of Niobium(V): Synthesis, Characterization and DFT Study, Eur. J. Inorg. Chem., 3112-3118 (2013).

165)    F. Marchetti, G. Pampaloni, S. Zacchini, Lactam/MoCl5 Interaction in CH2Cl2: synthesis and X-ray Characterization of Protonated d-Valerolactam Salts, RSC Advances, 3, 10007-10013 (2013).

166)    M. Hayatifar, F. Marchetti, G. Pampaloni, S. Zacchini, Reactions of Molybdenum Pentachloride with Oxygen and Nitrogen Donor Ligands, Polyhedron, 61, 188-194 (2013).

167)    M. Bortoluzzi, F. Marchetti, G. Pampaloni, M. Pucino, S. Zacchini, Coordination Complexes of NbX5 (X = F, Cl) with (O,N)- and (O,O)-Donor Ligands and the First X-Ray Characterization of a Mononuclear NbF5 Adduct, Dalton Trans, 42, 13054-13064 (2013)

168)    T. Funaioli, F. Marchetti, G. Pampaloni, S. Zacchini, Ligand-Interchange Reactions Between M(IV) (M = Ti, V) Oxide Bis-Acetylacetonates and Halides of High Valent Groups 4 and 5 Metals. A Synthetic and Electrochemical Study, Dalton Trans, 42, 14168 – 14177 (2013).

169)    F. Marchetti, G. Pampaloni, C. Pinzino Long-Lived Radical Cation Salts Obtained by Interaction of Monocyclic Arenes with Niobium and Tantalum Pentahalides at Room Temperature: EPR and DFT Studies, Chem. Eur. J., 19, 12962-13969 (2013).

170)    C. Forte M. Hayatifar, G. Pampaloni, A. M. Raspolli Galletti, F. Renili, S. Zacchini, Titanium Complexes Bearing Carbamato Ligands as Catalytic Precursors for Propylene Polymerization Reactions, J. Polym. Sci., Part A: Polymer Chem.,51, 4095-4102 (2013).

171)    F. Marchetti, G. Pampaloni, C. Pinzino, S. Zacchini, Stable [M2F11] (M = Nb, Ta) Salts of Protonated 1,3-Dimethoxybenzene, Eur. J. Inorg. Chem., 5755-5761 (2013).

172)    F. Marchetti, G. Pampaloni, S. Zacchini, The Reactivity of Molybdenum Pentachloride with Ethers: Routes to the Synthesis of MoIVCl4 Adducts, Mo(V) Chlorido-Alkoxides and Mo(V) Oxydo-Chlorides, Dalton Trans., 42, 15226-15234 (2013).

173)    S. Dolci,  V. Ierardi, A. Gradišek, Z. Jagličić, M. Remskar, T. Apih, M. Cifelli, G. Pampaloni, C. A. Veracini and V. Domenici, Precursors of Magnetic Resonance Imaging Contrast Agents Based on Cystine-coated Iron-oxide Nanoparticles, Curr. Phys. Chem, 3 493-500 (2013).

174)    L. Favero, F. Marchetti, G. Pampaloni, S. Zacchini, The Interaction of Molybdenum Pentachloride with O- and S-Heterocycles, Dalton Trans., 43, 495-504 (2014).

175)    M. Hayatifar, F. Marchetti, G. Pampaloni, S. Zacchini, Reactions of TaF5 with Activated Arenes. Synthesis of [4-(OH)-3-(OCH3)C6H3CH(=O-H)][4-(OH)-3-(OCH3)C6H3CHO][TaF6], a Rare Example of Protonated Aldehyde, Polyhedron, 70, 6-10 (2014).

176)    M. Hayatifar, G. Pampaloni, L. Bernazzani, C. Capacchione, A. M. Raspolli Galletti, Y. Kissin, A new type of post-metallocene catalyst for alkene polymerization. Copolymerization of ethylene and 1-hexene with titanium complexes bearing N,N-dialkylcarbamato ligands, Polym. Int., 63, 560-567 (2014).

177)    M. Bortoluzzi, E. Ferretti, F. Marchetti, G. Pampaloni, S. Zacchini, A Structurally-Characterized NbCl5-NHC Adduct, Chem. Commun, 50, 4472-4474 (2014).

178)    M. Bortoluzzi, F. Marchetti, G. Pampaloni, S. Zacchini, Tribenzylamine C-H Activation and Intermolecular Hydrogen Transfer Promoted by WCl6, Inorg. Chem., 53, 3832-3838 (2014).

179)    M. Bortoluzzi, M. Hayatifar, F. Marchetti, G. Pampaloni, S. Zacchini, Synthesis of di- and tetranuclear oxidomolybdenum(V) complexes containing p-toluenesulfonates as ligands: a joint spectroscopic, crystallographic and computational study, Dalton Trans., 43, 10157-10163 (2014).

180)    S. Dolci, V. Domenici, C. Duce, M. R. Tiné, V. Ierardi, U. Valbusa, Z Jaglicic, A. Boni, M. Gemmi, G. Pampaloni, Ultrasmall superparamagnetic iron oxide nanoparticles with titanium-N,N-dialkylcarbamato coating, Mat. Res. Express, 1, 035401-035420 (2014)

181)    M. Bortoluzzi, F. Marchetti, G. Pampaloni, S. Zacchini, Oxido-molybdenum complexes obtained by Cl/O exchange between MoCl5 and carboxylic acids: a crystallographic, spectroscopic, and computational study, Dalton Trans., 43, 16416-16423 (2014).

182)    F. Marchetti, G. Pampaloni, S. Zacchini, A Simple Route to Thermally-Stable Salts of Pyrrolidinium-2-Carbonylchloride, RCS Advance, 4, 60878-60882 (2014)

183)    M. Bortoluzzi, F. Marchetti, M. G. Murrali, G. Pampaloni, Revisitation of the PCl5-Chlorination Reaction of a-Amino Acids: Spectroscopic and DFT Insights, and Synthesis of the L-Proline-Derived 2,5-Diketopiperazine, Inorg. Chim. Acta, 427, 150-154 (2015).

184)    M. Bortoluzzi, F. Marchetti, G. Pampaloni, S. Zacchini, A Crystallographically-Characterized Salt of Self-Generated N-Protonated Tetraethylurea, Chem. Commun., 51, 1323-1325 (2015).

185)    L. Biancalana, M. Bortoluzzi, C. Forte, F. Marchetti, G. Pampaloni, Structural Characterization of α-Amino Acid Complexes of Molybdates: a Spectroscopic and DFT Study, RCS Advance, 5, 9010-9018 (2015).

186)    F. Marchetti, G. Pampaloni, S. Zacchini, The reactivity of MoCl5 with molecules containing the alcohol functionality, Polyhedron, 85, 369-375 (2015).

187)    M. Bortoluzzi, F. Marchetti, M. G. Murrali, G. Pampaloni, S. Zacchini, The Chlorinating Power of WCl6 Towards α-Aminoacids: Synthesis and Structural Characterization of α-Ammonium-Acylchloride Salts and Mechanistic Studies on Their Activation, Dalton Trans., 44, 8729-8738 (2015)

188)    M. Bortoluzzi, M. Hayatifar,  F. Marchetti, G. Pampaloni, S. Zacchini, Synthesis of α-Amino Acidato Derivatives of Niobium and Tantalum Pentahalides and Their Conversion into Iminium Salts, Inorg. Chem., 54, 4047-4055 (2015).

189)    M. Bortoluzzi, G. Bresciani, F. Marchetti, G. Pampaloni, St. Zacchini, MoCl5 as an Effective Chlorinating Agent Towards a-Aminoacids: Synthesis of a-Ammonium-Acylchloride Salts and a-Amino-Acylchloride Complexes, Dalton Trans. 44, 10030-10037 (2015).

190)   F. P. Di Nicola, M. Lanzi, F. Marchetti, G. Pampaloni, S. Zacchini, Is Bond Stretch Isomerism in Mononuclear Transition Metal Complexes a Real Issue? The Misleading Case of the MoCl5/Tetrahydropyran Reaction System, Dalton Trans, 44, 12653-12659 (2015).

191)    G. Agonigi, T. Riedel, S. Zacchini, E. Păunescu, G. Pampaloni, N. Bartalucci, P. J. Dyson, F.Marchetti, Synthesis and Antiproliferative Activity of New Ruthenium Complexes with Ethacrynic Acid-Modified Pyridine- and Triphenylphosphine-Ligands, Inorg. Chem., 54, 6504-6512 (2015).

192)    M. Bortoluzzi, F. Guarra, F. Marchetti, G. Pampaloni, S. Zacchini, Different outcomes in the reactions of WCl6 with carboxylic acids, Polyhedron, 99, 141-146 (2015).

193)    R. Bondi, F. Marchetti, G. Pampaloni, S. Zacchini, The versatile chemistry of niobium pentachloride with aliphatic amines: aminolysis, metal reduction and C-H activation, Polyhedron, 100, 192-198 (2015).

194)    E. Ferretti, M. Hayatifar, F. Marchetti, G. Pampaloni, S. Zacchini, Molybdenum(V) and Molybdenum(IV) coordination compounds from the reactions of MoCl5 with sulfones, Polyhedron, 100, 400-403 (2015).

195)    C. Duce, A. Spepi, G. Pampaloni, F. Piccinelli, M. R. Tiné, Thermal decomposition of metal N,N-dialkylcarbamates. A TG-FTIR study,  J. Therm. Anal. Calorim., 123, 1563-1569 (2016).

196)    C. Evangelisti, M. Hayatifar, F. Marchetti, M. Marelli, G. Pampaloni, F. Piccinelli, Synthesis of Nanocrystalline TiOF2 Embedded in a Carbonaceous Matrix from TiF4 and D-Fructose, Inorg. Chem., 55, 1816-1820 (2016).

197)    G. Agonigi, T. Riedel, M. P. Gay, L. Biancalana, E. Oñate, P. J. Dyson, G. Pampaloni, E. Păunescu, M. A. Esteruelas, F. Marchetti, Arene Osmium Complexes with Ethacrynic Acid-Modified Ligands: Synthesis, Characterization and Evaluation of Intracellular Glutathione S-transferase Inhibition and Antiproliferative Activity, Organometallics, 35, 1046–1056 (2016).

198)    M. Bortoluzzi, E. Ferretti, F. Marchetti, G. Pampaloni, S. Zacchini, Coordination Complexes of Niobium and Tantalum Pentahalides with a Bulky NHC Ligand, Dalton Trans., 45, 6939-6948 (2016).

199)    M. Bortoluzzi, E. Ferretti, F. Marchetti, G. Pampaloni, C.- Pinzino, S. Zacchini, Coordination Compounds of Niobium(IV) Oxide Dihalides Including the Synthesis and the Crystallographic Characterization of NHC Complexes, Inorg. Chem., 55, 4173–4182 (2016).

200)    M. Bortoluzzi, F. Marchetti, G. Pampaloni, S. Zacchini, The Reactivity of WCl6 with Ethers: a Joint Computational, Spectroscopic and Crystallographic Study, Eur. J. Inorg. Chem., 3169-3177 (2016).

201)    M. Bortoluzzi, F. Foschi, F. Marchetti, G. Pampaloni, S. Zacchini, Electron Exchange Reactions Between Tungsten Hexachloride and Aliphatic Amines, Polyhedron, 115, 30-36 (2016)

202)    F. Marchetti, G. Pampaloni, S. Zacchini, The Reactivity of Niobium and Tantalum Pentahalides with Imines, Polyhedron, 115, 99-104(2016)

203)    M. Bortoluzzi, F. Marchetti, G. Pampaloni, C. Pinzino, S. Zacchini, Oxydative Dimerization of Triarylamines Promoted by WCl6, Including the Solid State Isolation and the Crystallographic Characterization of a Triphenylammonium Salt, Inorg. Chem., 55, 887-893 (2016).

204)    M.Bortoluzzi, E. Ferretti, M. Hayatifar, F. Marchetti, G. Pampaloni, S. Zacchini, One Pot Intermolecular C-S Self Coupling of Dimethylsulfoxide Promoted by Molybdenum Pentachloride, Eur. J. Inorg. Chem., 3838-3845 (2016).

205)    S. Bianchi, M. Bortoluzzi, V. Castelvetro, F. Marchetti, G. Pampaloni, C. Pinzino, S. Zacchini, The Reactivity of Tungsten Hexachloride with Tetrahydrofuran and 2-Methoxyethanol, Polyhedron, 117, 769-776 (2016)

206)    M.Bortoluzzi, E. Ferretti, F. Marchetti, G. Pampaloni, S. Zacchini, A Crystallographic and DFT Study on a NHC complex of niobium oxide trifluoride, J. Coord, Chem., 69, 2766-2774 (2016).

207)    M.Bortoluzzi, F. Marchetti, G. Pampaloni, S. Zacchini, The Chemistry of high valent tungsten chlorides with N-substituted ureas, including urea self-protonation reactions triggered by WCl6, New J. Chem., 40, 8271-8281 (2016).

208)    Synthesis of a highly reactive form of WO2Cl2, its conversion into nanocrystalline mono-hydrated WO3 and coordination compounds with tetramethylurea, Dalton Trans., 45, 15342-15349 (2016).